Salomé was drafted by the Milwaukee Brewers in the fifth round of the 2004 Major League Baseball draft from George Washington High School in New York, New York. He made his professional baseball debut that summer playing for the Rookie Arizona League Brewers.
In 2005, Salomé played for the Helena Brewers of the Rookie Pioneer League and the Class A West Virginia Power in the South Atlantic League. He led the Pioneer League with a .415 batting average. Salomé won the Pioneer League Most Valuable Player Award, was named to its postseason All-Star team, and chosen as a Baseball America Rookie All-Star. He played the entire 2006 season at West Virginia, where he was selected for the South Atlantic League's midseason and postseason All-Star teams. In 2007, he was promoted to the Class A-Advanced Brevard County Manatees in the Florida State League. Salomé reached Double-A in 2008, playing in the Southern League for the Huntsville Stars. He led the circuit with a .360 average and was selected for the league's midseason and postseason All-Star squads and was chosen as a Baseball America Double-A All-Star.
Salomé was a September call-up after the season at Huntsville and made his major league debut with the Milwaukee Brewers on September 3, 2008. Pinch-hitting for the pitcher in the seventh inning, Salomé flew out in his only at bat. He pinch hit in two other games that season, striking out on September 7 and grounding out on September 13. These three were to be his only major league plate appearances. After the season, he participated in the Arizona Fall League with the Peoria Javelinas.

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