Born and raised in Bayonne, Daly attended the University of Maryland, College Park. He received his medical training at Baltimore Medical College (since renamed University of Maryland Medical Center Midtown Campus).
Connie Mack recruited Daly in 1902 to play for the Newark Sailors minor league baseball team in the Eastern League. He played major league baseball in 1903 with the Philadelphia Athletics while he was still a student in medical school. From 1903 to 1906, Daly played for the Hartford Senators of the Connecticut League.
He was appointed in 1920 to serve as the physician of Hudson County, New Jersey, serving in that role until 1938.

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