Duensing went to Millard South High School in Omaha, Nebraska, where he earned second-team All-State honors in both his junior and senior years. His senior year he batted .429, and went 2–2 with a 3.78 earned run average on the mound. His combined record in two seasons of American Legion ball was 16–3 with 141 strikeouts. He had a 0.74 ERA, and a .522 batting average his second season.\n', '

Duensing was a college teammate of New York Yankees pitcher Joba Chamberlain and Kansas City Royals left fielder Alex Gordon at the University of Nebraska.\n', '

In 2002 as a freshman, Duensing went 6–2 with a 4.73 ERA and 60 strikeouts (versus 25 walks) in 78 innings over 18 appearances (12 starts). He replaced Shane Komine in the starting rotation in Big 12 play while Komine was injured. He won 6 games in a row before losing to Richmond in the Super Regional. He helped the Huskers reach the 2002 College World Series throwing 11.2 consecutive scoreless innings in the NCAA Regional and Super Regional until allowing three runs in the 9th inning. He was an honorable-mention freshman all-American and was on the Big 12 all-freshman team.\n', '

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