Nicdao attended Victorian College of Arts and studied jazz and classical music. After an audition for a role in which she did not get the part, Nicdao discovered that her true love was acting.
Nicdao's big break happened in 2008 when she was cast as Jackie in A gURLs wURLd. Nicdao auditioned when she was 17. The show filmed in Sydney, Singapore, and Hamburg, so Nicdao completed the final year of high school by distance education with the goal to return to Melbourne and make a career out of jazz singing.
In 2014, Nicdao joined the second season cast of Josh Thomas' Australian TV series Please Like Me, and played the role of Tom's girlfriend Jenny.

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