She won the World Junior Girls Chess Championship in 2012. This achievement earned her the qualification for the Women's World Championship 2014, which was eventually postponed to 2015.
Guo competed in the Women's World Chess Championship 2012 as FIDE president nominee. She was eliminated in the first round by Natalia Zhukova.
Guo was a member of the Chinese team that won the silver medal in the 2013 Women's World Team Chess Championship in Astana, Kazakhstan. In 2014, she won both team and individual (on the reserve board) silver medals in the Women's 2014 Chess Olympiad.

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