Jaime signed as an amateur free agent with the Washington Nationals. In 2007, Jaime pitched for the Nationals team in the rookie-level Dominican Summer League. He logged a total of 26⅔ innings in 14 relief appearances, winning 3 games, losing none, and recording a 1.35 ERA. During this span, he struck out 34 batters while issuing just 14 bases on balls.\n', '

Following the 2010 season, Jaime was claimed off waivers from the Nationals by the Arizona Diamondbacks. He was designated for assignment on August 13, 2011, \n', '

He subsequently signed a minor league contract with the Atlanta Braves on August 18.\n', '

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