Langwell attended Rice University. In 2007, he played collegiate summer baseball with the Wareham Gatemen of the Cape Cod Baseball League.
Langwell was drafted by the Cleveland Indians in the 11th round of the 2008 Major League Baseball Draft. He was called up to the majors for the first time on June 1, 2013. He was optioned back to the Triple-A Columbus Clippers on June 18.
The Arizona Diamondbacks received Langwell on September 1 as the player to be named later in the August 30, 2013 trade for Jason Kubel. He was outrighted off the roster on October 3, 2013. He was released on March 17, 2014.

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