Maestro was born in Buenos Aires, Argentina in 1978. She made her screen debut in Carlos Saura’s Tango, which received Golden Globe and Academy Award nominations for Best Foreign Film. Initially trained in Argentina, Maestro traveled to Berlin to develop a vocal repertoire of the works of Kurt Weill and Hanns Eisler. Her first proper acting turn was in the play The Summer Trilogy by Carlo Goldoni, and by 1998, she secured the coveted role of Lulu in Frank Wedekind’s Pandora’s Box at the San Martin Theater in her hometown of Buenos Aires. For this she garnered an "Ace" Award for Best New Artist of the Year.\n', '

In 2004, she joined the cast of ABC’s critically acclaimed series Alias for two seasons. In the same year, Maestro also appeared in the Argentine film La Niña Santa (aka The Holy Girl), directed by Lucrecia Martel, as well as the Focus Features film The Motorcycle Diaries, (Golden Globe nominee in 2005 for Best Foreign Film) based on the journals of Che Guevara, leader of the Cuban Revolution. The film was directed by Walter Salles (Central Station), and stars Gael García Bernal and Rodrigo de la Serna. Maestro has starred as a victim of a kidnapping in Venezuela in Jonathan Jakubowicz’s thriller Secuestro Express, released by Miramax. In December 2005, she starred in Prince\'s music video for "Te Amo Corazón", which was directed by her friend Salma Hayek.\n', '

In 2006, she co-starred in Wolfgang Petersen\'s film Poseidon, a remake of the 1972 film of the same name. She played Elena Gonzalaz, a stowaway girl going to meet her sick brother in the hospital with friend and waiter Valentine.\n', '

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