Masset had minor league stints with the Single-A Stockton Ports, Double-A Frisco RoughRiders and Triple-A Oklahoma RedHawks prior to his first call-up in June 2006.\n', '

Masset was traded to the Chicago White Sox on December 23, 2006, along with John Danks and Jacob Rasner for Brandon McCarthy and David Paisano.\n', '

On July 31, 2008, Masset, along with infielder Danny Richar, was traded to the Cincinnati Reds for Ken Griffey Jr. After the trade Masset appeared in 10 games for the Reds going 1–0 with an ERA of 2.08 in ​17 1⁄3 innings. The 2009 season saw Masset going 5–1 in 76 innings with an earned run average of 2.37. In 2010 Masset went 4–4 in ​76 2⁄3 with an ERA of 3.40. In 2011 Masset went 3–6 in ​70 1⁄3 innings to an ERA of 3.71. At the start of the 2012 Masset was sidelined with right shoulder injury. He would not pitch all year before having surgery on September 7 to repair a torn anterior capsule. Masset was expected to be ready for the start of the 2013 season but would again miss the entire season. Masset had surgery to correct thoracic outlet syndrome.\n', '

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