Leibman also acted in films such as Where's Poppa? (1970), The Hot Rock (1972), Norma Rae (1979), and Zorro, The Gay Blade (1982). Later in his career, he became widely known for providing the voice of Ron Cadillac in Archer (2013–2021) and for playing Dr. Leonard Green, Rachel's rich, short-tempered father, on the sitcom Friends (1996–2004).
Leibman was born in Manhattan to Grace (née Marks), who was of Russian-Jewish descent, and Murray Leibman, a Russian Jewish immigrant who worked in the garment business. Leibman graduated from Ohio Wesleyan University.
Leibman was a member of the Compass Players in the late 1950s, and was admitted to the Actors Studio shortly thereafter.

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