Green signed with the Montreal Alouettes in May 2007 following the 2007 NFL Draft. His first career Canadian Football League (CFL) reception came on June 29, 2007 against the Saskatchewan Roughriders. His first career touchdown was against the Edmonton Eskimos on October 31, 2008, which was the fifth game of his professional career. Green was a member of both the 97th Grey Cup and 98th Grey Cup championship team with the Montreal Alouettes.
Six days before signing a future contract with the New York Jets on January 9, 2010, Green was listed as a "CFL player of interest to the NFL" by The Globe and Mail.
On May 18, 2010, the Jets released Green, following the first team Organized Team Activities practice of the year.

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