Chapman attended Bishop Kenny High School in Jacksonville, Florida. He enrolled at Mississippi State University, where he played college baseball for the Mississippi State Bulldogs. He played collegiate summer baseball with the Orleans Cardinals of the Cape Cod Baseball League in 1998. He was drafted by the Phillies in the 17th round of the 2000 Major League Baseball draft and played his first professional season with the Batavia Muckdogs of the New York-Penn League.
The Phillies promoted Chapman to the major leagues on September 2, 2003. He appeared in one MLB game, on September 9, 2003, against the Atlanta Braves. He pinch hit for Tomás Pérez in the seventh inning against Braves pitcher Jung Bong and flew out to right field. Chapman finished the game at third base.
Chapman spent seven seasons in the minor leagues with the Phillies, Kansas City Royals, Cincinnati Reds, and Pittsburgh Pirates organizations before retiring after the 2006 season. In 1,771 career minor league at bats, he hit .286, with 41 home runs.

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