Hembree played baseball and high school football at Broome High School in his hometown of Spartanburg, South Carolina. He was a standout pitcher and quarterback for Broome, but did not pitch as a senior in 2007, due to a knee injury suffered playing football. Instead, Hembree was a designated hitter his senior season; he had a .320 batting average.\n', '

Hembree initially attended the University of South Carolina, but only had one pitching appearance his entire freshman season in 2008. He then transferred to Spartanburg Methodist College, a junior college that is part of the National Junior College Athletic Association. As a transfer sophomore, he went 7–0 with a 1.22 earned run average (ERA). After receiving a scholarship to the College of Charleston, an NCAA Division I school, Hembree transferred there, where he spent his final season of college baseball.\n', '

Hembree was drafted in the fifth round of the 2010 MLB Draft by the San Francisco Giants.\n', '

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